Methods and systems for suppressing pyrophoric metal fires

ABSTRACT

A method for suppressing a pyrophoric metal fire may include arranging a suppression system above a containment structure. The suppression system includes a first extinguishing agent. The containment structure is configured to contain and isolate a pyrophoric metal from ambient air. The suppression system is configured to activate upon a leak and ignition of the pyrophoric metal so as to release the first extinguishing agent to suppress the pyrophoric metal fire.

BACKGROUND

Field

The present disclosure relates to methods and associated systems for thesuppression of metallic fires.

Description of Related Art

A liquid metal-cooled nuclear reactor, also referred to as a liquidmetal fast reactor (LMFR), is a fast neutron nuclear reactor where theprimary coolant is a liquid metal. Various types of liquid metals withrelatively high heat capacities (which provide thermal inertia againstoverheating) may be used as the primary coolant. An example of a liquidmetal-cooled nuclear reactor is a sodium-cooled fast reactor (SFR). In asodium-cooled fast reactor (SFR), liquid sodium is used as the primarycoolant instead of water. Water is difficult to use as a coolant for afast reactor, because water acts as a neutron moderator that slows thefast neutrons into thermal neutrons. In contrast, sodium atoms are muchheavier than both the oxygen and hydrogen atoms found in water. As aresult, the neutrons lose less energy in collisions with sodium atoms.Sodium also need not be pressurized since its boiling point is muchhigher than the reactor's operating temperature. Furthermore, sodiumdoes not corrode steel reactor parts.

A potential concern for a sodium-cooled fast reactor (SFR) is theleakage of sodium. Sodium is a pyrophoric metal and will ignitespontaneously when contacted with air and/or water. The exothermicreaction of sodium with air and water is shown below by the followingequations.2Na(l)+O₂(g)→Na₂O₂(s)4Na(l)+O₂(g)→2Na₂O(s)2Na(l)+2H₂O→2NaOH(aq)+H₂(g)Notably, sodium hydroxide (NaOH) is caustic and hydrogen (H₂) isflammable. Additionally, sodium peroxide (Na₂O₂) and sodium oxide (Na₂O)will also form sodium hydroxide (NaOH) if contacted with water.

Conventionally, a metallic fire (e.g., sodium fire) in a nuclear reactoris extinguished by inerting the area where the pyrophoric metal (e.g.,sodium) is leaking. The inerting may be achieved with a vacuum pump thatis used to remove the air from the area of the leak while supplying aninert gas (e.g., nitrogen, argon) which does not react with thepyrophoric metal. By removing the reaction source (e.g., oxygen) fromthe area of the leak, the metallic fire may be extinguished. However,this inerting approach is dangerous to plant workers who may be in thearea of the leak and, thus, accidentally exposed to the oxygen-deficientenvironment.

SUMMARY

A method for suppressing a pyrophoric metal fire may include arranging asuppression system above a containment structure. The suppression systemincludes a first extinguishing agent. The containment structure isconfigured to contain and isolate a pyrophoric metal from ambient air.The suppression system is configured to activate upon a leak andignition of the pyrophoric metal so as to release the firstextinguishing agent to suppress the pyrophoric metal fire.

BRIEF DESCRIPTION OF THE DRAWINGS

The various features and advantages of the non-limiting embodimentsherein may become more apparent upon review of the detailed descriptionin conjunction with the accompanying drawings. The accompanying drawingsare merely provided for illustrative purposes and should not beinterpreted to limit the scope of the claims. The accompanying drawingsare not to be considered as drawn to scale unless explicitly noted. Forpurposes of clarity, various dimensions of the drawings may have beenexaggerated.

FIG. 1 is a view of a coating-type suppression system as implemented ina nuclear reactor according to an example embodiment of the presentdisclosure.

FIG. 2 is a view of a spray-type suppression system in conjunction witha coating-type suppression system as implemented in a nuclear reactoraccording to an example embodiment of the present disclosure.

FIG. 3 is a view of an I-beam-type suppression system according to anexample embodiment of the present disclosure.

FIG. 4 is a view of an I-beam-type suppression system as implemented ina nuclear reactor according to an example embodiment of the presentdisclosure.

FIG. 5 is a view of a tube-type suppression system according to anexample embodiment of the present disclosure.

FIG. 6 is a circuit diagram of a photodetector for a suppression systemaccording to an example embodiment of the present disclosure.

FIG. 7 is a view of a tube-type suppression system as implemented in anuclear reactor according to an example embodiment of the presentdisclosure.

FIG. 8 is a view of an I-beam-type suppression system in conjunctionwith a tube-type suppression system as implemented in a nuclear reactoraccording to an example embodiment of the present disclosure.

DETAILED DESCRIPTION

It should be understood that when an element or layer is referred to asbeing “on,” “connected to,” “coupled to,” or “covering” another elementor layer, it may be directly on, connected to, coupled to, or coveringthe other element or layer or intervening elements or layers may bepresent. In contrast, when an element is referred to as being “directlyon,” “directly connected to,” or “directly coupled to” another elementor layer, there are no intervening elements or layers present. Likenumbers refer to like elements throughout the specification. As usedherein, the term “and/or” includes any and all combinations of one ormore of the associated listed items.

It should be understood that, although the terms first, second, third,etc. may be used herein to describe various elements, components,regions, layers and/or sections, these elements, components, regions,layers, and/or sections should not be limited by these terms. Theseterms are only used to distinguish one element, component, region,layer, or section from another region, layer, or section. Thus, a firstelement, component, region, layer, or section discussed below could betermed a second element, component, region, layer, or section withoutdeparting from the teachings of example embodiments.

Spatially relative terms (e.g., “beneath,” “below,” “lower,” “above,”“upper,” and the like) may be used herein for ease of description todescribe one element or feature's relationship to another element(s) orfeature(s) as illustrated in the figures. It should be understood thatthe spatially relative terms are intended to encompass differentorientations of the device in use or operation in addition to theorientation depicted in the figures. For example, if the device in thefigures is turned over, elements described as “below” or “beneath” otherelements or features would then be oriented “above” the other elementsor features. Thus, the term “below” may encompass both an orientation ofabove and below. The device may be otherwise oriented (rotated 90degrees or at other orientations) and the spatially relative descriptorsused herein interpreted accordingly.

The terminology used herein is for the purpose of describing variousembodiments only and is not intended to be limiting of exampleembodiments. As used herein, the singular forms “a,” “an,” and “the” areintended to include the plural forms as well, unless the context clearlyindicates otherwise. It will be further understood that the terms“includes,” “including,” “comprises,” and/or “comprising,” when used inthis specification, specify the presence of stated features, integers,steps, operations, elements, and/or components, but do not preclude thepresence or addition of one or more other features, integers, steps,operations, elements, components, and/or groups thereof.

Example embodiments are described herein with reference tocross-sectional illustrations that are schematic illustrations ofidealized embodiments (and intermediate structures) of exampleembodiments. As such, variations from the shapes of the illustrations asa result, for example, of manufacturing techniques and/or tolerances,are to be expected. Example embodiments should not be construed aslimited to the shapes of regions illustrated herein but are to includedeviations in shapes that result, for example, from manufacturing. Thus,the regions illustrated in the figures are schematic in nature and theirshapes are not intended to illustrate the actual shape of a region of adevice and are not intended to limit the scope of example embodiments.

Unless otherwise defined, all terms (including technical and scientificterms) used herein have the same meaning as commonly understood by oneof ordinary skill in the art to which example embodiments belong. Itwill be further understood that terms, including those defined incommonly used dictionaries, should be interpreted as having a meaningthat is consistent with their meaning in the context of the relevant artand will not be interpreted in an idealized or overly formal senseunless expressly so defined herein.

A method for suppressing a pyrophoric metal fire according to exampleembodiments may include arranging a suppression system above acontainment structure. The suppression system includes a firstextinguishing agent, and the containment structure is configured tocontain and isolate a pyrophoric metal from ambient air. The suppressionsystem is configured to activate upon a leak and ignition of thepyrophoric metal so as to release the first extinguishing agent tosuppress the pyrophoric metal fire.

FIG. 1 is a view of a coating-type suppression system as implemented ina nuclear reactor according to an example embodiment of the presentdisclosure. Referring to FIG. 1, a coating-type suppression system 100includes a fire extinguishing agent 102 (e.g., first extinguishingagent) and is disposed on a stable surface above a containment structure104. The stable surface may be the ceiling of a chamber that houses thecontainment structure 104.

The containment structure 104 may be a steam generator of a liquid metalfast reactor and may include liquid metal inlet pipes 106, liquid metaloutlet pipes 108, feedwater inlet pipes 110, and a steam outlet pipe112, although example embodiments are not limited thereto. Thecontainment structure 104 is configured to contain and isolate, interalia, a pyrophoric metal from the ambient air. For instance, thepyrophoric metal may be an alkali metal. In a non-limiting embodiment,the alkali metal may be sodium.

As shown in FIG. 1, a leak 114 may occur in one or more of the liquidmetal inlet pipes 106. However, it should be understood that the leak114 may occur in other parts of the containment structure 104. Where thecontainment structure 104 contains a pyrophoric metal (e.g., sodium), ametallic fire may spontaneously occur when the pyrophoric metal leaksand comes into contact with oxygen and/or water (e.g., via the ambientair).

The coating-type suppression system 100 may be heat-activated and/orchemically-activated by the pyrophoric metal fire. For instance, thecoating-type suppression system 100 may be configured such that astructural integrity thereof degrades in a presence of the pyrophoricmetal fire in order to release the fire extinguishing agent 102. Forsmaller fires, the scope of the degradation may be limited to thevicinity of the coating-type suppression system 100 above the pyrophoricmetal fire such that only a portion of the fire extinguishing agent 102in that area is released and falls down onto the pyrophoric metal fireto suppress such combustion. On the other hand, for larger fires, a moreextensive amount of the coating-type suppression system 100 may degradeand release the fire extinguishing agent 102 therein onto the combustionregion(s). Thus, the coating-type suppression system 100 is relativelyflexible in its ability to suppress or extinguish metallic fires ofvarious sizes and at varying locations.

The structural integrity of the coating-type suppression system 100 maybe configured to deteriorate when a surface of the coating-typesuppression system 100 reaches an elevated temperature as a result ofexposure to the pyrophoric metal fire. For instance, the structuralintegrity of the coating-type suppression system 100 may be configuredto break down when the elevated temperature at the surface of thecoating-type suppression system 100 reaches 75 degrees Celsius or more.

In addition to (or in lieu of) being heat-activated, the structuralintegrity of the coating-type suppression system 100 may be configuredto deteriorate when exposed to one or more reaction byproducts of thepyrophoric metal fire. For instance, the structural integrity of thecoating-type suppression system 100 may be configured to becomeembrittled when the one or more reaction byproducts includes hydrogengas. In a non-limiting embodiment, the structural integrity of thecoating-type suppression system 100 may be configured to break down whena concentration of the hydrogen gas reaches 50 pphm or more.

The coating-type suppression system 100 may be in the form of acontinuous, conformal layer that is positioned (e.g., adhered to theceiling) such that the fire extinguishing agent 102 will fall on thepyrophoric metal fire via gravity when released. For instance, thecoating-type suppression system 100 may be configured as a polymer layerthat includes the fire extinguishing agent 102, wherein the polymerlayer is applied on a ceiling above the containment structure 104. Thepolymer layer may include the following structure

wherein X is a chlorine, a carbonate, or another atom/molecule that willreact with the pyrophoric metal (e.g., Na) to form a thermodynamicallystable product (e.g., NaCl, Na₂CO₃). However, it should be understoodthat other materials (that provide suitable heat-activation and/orchemical-activation properties) may also be used.

FIG. 2 is a view of a spray-type suppression system in conjunction witha coating-type suppression system as implemented in a nuclear reactoraccording to an example embodiment of the present disclosure. Referringto FIG. 2, a spray-type suppression system 200 may be used alone ortogether with the coating-type suppression system 100 of FIG. 1 in orderto suppress or extinguish any metallic fires that result from the leak114 of a pyrophoric metal. The spray-type suppression system 200 may beactively controlled to allow a dispensing end thereof to spray a secondextinguishing agent directly at the leak to suppress or extinguish themetallic fire. The second extinguishing agent may be the polymermaterial discussed in connection with FIG. 1, although exampleembodiments are not limited thereto. For instance, the secondextinguishing agent may be Met-L-X. With regard to being configured foractive control, the dispensing end of the spray-type suppression system200 may be rotated and/or angled as needed. Additionally, one or moreportions of the spray-type suppression system 200 may be extended and/orretracted as needed in order to reach a desired location. Although thespray-type suppression system 200 is shown in FIG. 2 as including asingle spray structure that extends from the ceiling, it should beunderstood that example embodiments are not limited thereto. Forinstance, the spray-type suppression system 200 may include a pluralityof spray structures. Additionally, one or more of the spray structuresmay be configured to extend from one or more of the ceiling, sidewalls,and/or floor. The spray-type suppression system 200 may be particularlyuseful for suppressing or extinguishing larger and/or continuingmetallic fires.

FIG. 3 is a view of an I-beam-type suppression system according to anexample embodiment of the present disclosure. Referring to FIG. 3, theI-beam-type suppression system 300 includes an I-beam structure 302 anda container secured to the bottom thereof. The container may be a metalcasing (e.g., titanium sheet) that encloses a fire extinguishing agenttherein. The metal casing may be formed to include defects and infusedwith hydrogen diffusion promoters (e.g., CN⁻) in order to facilitaterapid deterioration of the container due to embrittlement via hydrogendiffusion. In an example embodiment, the metal casing may be configuredas a partial-cylindrical container 304 and secured to a bottom of theI-beam structure 302. However, it should be understood that the metalcasing may be configured into a variety of other suitable shapes. Thefire extinguishing agent within the metal casing may be a salt-basedpowder (e.g., Met-L-X) or a graphite-based powder. Additionally, thefire extinguishing agent may include a weak acid (e.g., boric acid).

FIG. 4 is a view of an I-beam-type suppression system as implemented ina nuclear reactor according to an example embodiment of the presentdisclosure. Referring to FIG. 4, the I-beam-type suppression system 300of FIG. 3 may be implemented in a liquid metal fast reactor. Forinstance, the I-beam structure 302 may be an existing structure that isalready used to support the ceiling of the chamber housing thecontainment structure, wherein the partial-cylindrical container 304 issubsequently secured to the bottom of the I-beam structure 302 to formthe I-beam-type suppression system 300. Alternatively, the combinationof the I-beam structure 302 and the partial-cylindrical container 304may already be first secured together to form the I-beam-typesuppression system 300 and then brought into the chamber and mounted onthe ceiling.

During operation of the liquid metal fast reactor, a pyrophoric metalwithin the containment structure may leak and cause a metallic fire. TheI-beam-type suppression system 300 may be heat-activated and/orchemically-activated by the metallic fire. For example, as a result ofthe metallic fire, hydrogen gas may be produced so as to deteriorate theintegrity of the partial-cylindrical container 304, thereby releasingthe fire extinguishing agent therein.

FIG. 5 is a view of a tube-type suppression system according to anexample embodiment of the present disclosure. Referring to FIG. 5, thetube-type suppression system 500 may include a metal casing that isconfigured as a tubular container 502. The metal casing may be formed toinclude defects and infused with hydrogen diffusion promoters (e.g.,CN⁻) in order to facilitate rapid deterioration of the container due toembrittlement via hydrogen diffusion. The tubular container 502 includestherein a fire extinguishing agent and a photodetector 504. The fireextinguishing agent may be a salt-based powder (e.g., Met-L-X) or agraphite-based powder. Additionally, the fire extinguishing agent mayinclude a weak acid (e.g., boric acid). The photodetector 504 isconfigured to indicate whether there is degradation of the metal casingby detecting whether light is entering the metal casing.

FIG. 6 is a circuit diagram of a photodetector for a suppression systemaccording to an example embodiment of the present disclosure. Referringto FIG.6, a phototransistor 602 is connected to a first load resistor604 and an amplifier 606. The amplifier 606 together with a second loadresistor 608 (e.g., 10 kΩ) and a third load resistor 610 (e.g., 1 kΩ)form a pre-amplifier 612. The pre-amplifier 612 is connected to ananalog-to-digital signal controller 614. Furthermore, theanalog-to-digital signal controller 614 is connected to a firstindicator light 616 and a second indicator light 618. In a non-limitingembodiment, the photodetector 504 in FIG. 5 may be as provided by thecircuit diagram of FIG. 6.

During operation of the liquid metal fast reactor, if the tubularcontainer begins to degrade, light will enter and activate thephotodetector therein. In particular, referring to FIG. 6, when light isdetected by the phototransistor 602, a corresponding voltage signal issent to the analog-to-digital signal controller 614, which controls thefirst indicator light 616 and the second indicator light 618. Thephototransistor 602 may be configured to detect light with anilluminance ranging between 1-1000 lux. If the tubular container is notdegraded and still intact, the first indicator light 616 (e.g., greenlight) will illuminate to indicate normal conditions. On the other hand,if the tubular container has begun to degrade and break, the secondindicator light 618 (e.g., red light) will illuminate to indicatedegradation.

FIG. 7 is a view of a tube-type suppression system as implemented in anuclear reactor according to an example embodiment of the presentdisclosure. Referring to FIG. 7, the tube-type suppression system 500 issecured to a ceiling above the containment structure. The tube-typesuppression system 500 is configured to be heat-activated and/orchemically-activated by a metallic fire.

FIG. 8 is a view of an I-beam-type suppression system in conjunctionwith a tube-type suppression system as implemented in a nuclear reactoraccording to an example embodiment of the present disclosure. Referringto FIG. 8, both the I-beam-type suppression system 300 and the tube-typesuppression system 500 are secured to a ceiling above the containmentstructure. Although FIG. 8 shows three tubular containers of thetube-type suppression system 500 being arranged between each I-beamstructure of the I-beam-type suppression system 300, it should beunderstood that example embodiments are not limited thereto. Forinstance, the number of tubular containers of the tube-type suppressionsystem 500 that can be arranged between each I-beam structure of theI-beam-type suppression system 300 will vary depending on the spacing ofthe I-beam structures as well as the size of the tubular containersthemselves.

While a number of example embodiments have been disclosed herein, itshould be understood that other variations may be possible. Suchvariations are not to be regarded as a departure from the spirit andscope of the present disclosure, and all such modifications as would beobvious to one skilled in the art are intended to be included within thescope of the following claims.

The invention claimed is:
 1. A method for suppressing a pyrophoric metalfire, comprising: arranging a suppression system above a containmentstructure, the suppression system including a first extinguishing agent,the containment structure configured to contain and isolate a pyrophoricmetal from ambient air, the suppression system configured to activateupon a leak and ignition of the pyrophoric metal so as to release thefirst extinguishing agent to suppress the pyrophoric metal fire, thesuppression system configured such that a structural integrity thereofdegrades in a presence of the pyrophoric metal fire in order to releasethe first extinguishing agent.
 2. The method of claim 1, wherein thestructural integrity of the suppression system is configured todeteriorate when a surface of the suppression system reaches an elevatedtemperature as a result of exposure to the pyrophoric metal fire.
 3. Themethod of claim 2, wherein the structural integrity of the suppressionsystem is configured to break down when the elevated temperature at thesurface of the suppression system reaches 75 degrees Celsius or more. 4.The method of claim 1, wherein the structural integrity of thesuppression system is configured to deteriorate when exposed to one ormore reaction byproducts of the pyrophoric metal fire.
 5. The method ofclaim 4, wherein the structural integrity of the suppression system isconfigured to become embrittled when the one or more reaction byproductsincludes hydrogen gas.
 6. The method of claim 5, wherein the structuralintegrity of the suppression system is configured to break down when aconcentration of the hydrogen gas reaches 50 pphm or more.
 7. The methodof claim 1, wherein the arranging includes positioning the suppressionsystem such that the first extinguishing agent falls on the pyrophoricmetal fire via gravity when released.
 8. A method for suppressing apyrophoric metal fire, comprising: arranging a suppression system abovea containment structure, the suppression system including a firstextinguishing agent, the containment structure configured to contain andisolate a pyrophoric metal from ambient air, the suppression systemconfigured to activate upon a leak and ignition of the pyrophoric metalso as to release the first extinguishing agent to suppress thepyrophoric metal fire, the suppression system configured as a polymerlayer including the first extinguishing agent, the polymer layer beingapplied on a ceiling above the containment structure.
 9. The method ofclaim 8, wherein the polymer layer includes the following structure

wherein X is a chlorine or a carbonate.
 10. The method of claim 1,wherein the suppression system is configured as a metal casing thatencloses the first extinguishing agent therein.
 11. The method of claim10, wherein the metal casing is configured as a partial-cylindricalcontainer and secured to a bottom of an I-beam structure.
 12. The methodof claim 10, wherein the metal casing is configured as a tubularcontainer and secured to a ceiling above the containment structure. 13.The method of claim 10, wherein the metal casing is formed to includedefects and is infused with hydrogen diffusion promoters.
 14. The methodof claim 10, wherein the metal casing includes a photodetector installedtherein, the photodetector configured to indicate whether there isdegradation of the metal casing by detecting whether light is enteringthe metal casing.
 15. The method of claim 10, wherein the firstextinguishing agent is a salt-based powder or a graphite-based powder.16. The method of claim 15, wherein the first extinguishing agentincludes a weak acid.
 17. The method of claim 1, wherein the pyrophoricmetal is an alkali metal.
 18. The method of claim 17, wherein the alkalimetal is sodium.
 19. The method of claim 1, further comprising: sprayingthe pyrophoric metal fire with a second extinguishing agent.